The synthesis of a novel DDPHC diazonium salt: Investigation of its usability in the determination of phenol and chlorophenols using CV, SWV and DPV techniques

Celik H. H., ÖZCAN S., MÜLAZIMOĞLU A. D., YILMAZ E., Mercimek B., ÇUKUROVALI A., ...More

INORGANIC CHEMISTRY COMMUNICATIONS, vol.116, 2020 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 116
  • Publication Date: 2020
  • Doi Number: 10.1016/j.inoche.2020.107893
  • Journal Name: INORGANIC CHEMISTRY COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Academic Search Premier, Chimica, DIALNET
  • Keywords: DDPHG-DAS, Cyclic voltammetry, Square wave voltammetry, Differential pulse voltammetry, Chemical sensor electrode, GLASSY-CARBON ELECTRODE, ELECTROCHEMICAL OXIDATION, CYCLIC VOLTAMMETRY, GRAPHENE OXIDE, ELECTROOXIDATION, SURFACE, NANOCOMPOSITE, QUERCETIN, BEHAVIOR, 4-CHLOROPHENOL
  • Anadolu University Affiliated: Yes

Abstract

Electrochemical and spectroelectrochemical properties of newly synthesized diazonium salt of 2-(2-(1,3-dioxo- 3,3a-dihydro-1H-isoindol-2(7aH)-yl)-1-(3 methyl-3-phenylcyclobutyl)ethylidene) hydrazinecarboxamide (DDPHC-DAS) were studied using glassy carbon (GC) electrode. In the current study, surface characterization was performed by cyclic voltammetry (CV). Besides electrochemical impedance spectroscopy (EIS) was used for the electrochemical and spectroelectrochemical characterization. Surface images were obtained using scanning electron microscopy (SEM). After completion of modification and characterization process, DDPHC-DAS surface was examined for the usability for the quantitative determination of phenol and chlorophenol derivatives by using CV, square wave voltammetry (SWV) and differential pulse voltammetry (DPV). Phenol and chlorophenol solutions that were prepared in Britton-Robinson (BR) buffer solution (pH 8-12) were employed in this research. The presented study proves that all of compounds can be quantitatively determined not only simultaneously but also independently.