Hydrothermal Synthesis and Crystal Structure of Novel Oxovanadium Coordination Polymer: [((VO)-O-IV)(2)(OH)(2)(C10H6(COO)(2))](infinity)

ÇEVİK S., Alkaya Z. A., DAL H., SARI M.

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, cilt.46, sa.9, ss.1426-1431, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 46 Sayı: 9
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1080/15533174.2015.1137007
  • Dergi Adı: SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1426-1431
  • Anahtar Kelimeler: coordination polymer, naphthalenedicarboxylic acid, oxovanadium compounds, MOF, paramagnetic compound, INORGANIC-ORGANIC HYBRID, SUPRA-MOLECULAR FRAMEWORK, MAGNETIC-PROPERTIES, COMPLEXES
  • Anadolu Üniversitesi Adresli: Evet

Özet

A novel coordination polymer [((VO)-O-IV)(2)(OH)(2)(C10H6(COO)(2))](infinity) based on vanadium(IV) and 2,6-naphthalenedicarboxylato ligand has been prepared by hydrothermal synthetic method. The compound was characterized by elemental analysis, thermogravimetric analysis, Fourier Transform infrared spectroscopy, room-temperature magnetic susceptibility measurement, manganometric titration, bond valance sum calculations (BVS), and single-crystal X-ray diffraction method. BVS calculations, manganometric titration, and room-temperature magnetic susceptibility measurement showed that the compound has paramagnetic property due to tetravalent vanadium ions. The single-crystal structure analysis of the compound illustrates a 2D metal organic framework structure. Coordination geometry of vanadium ions was a distorted square-pyramid (square-pyramidal coordination environment of oxygen atoms). The compound represents a novel 2D inorganic-organic coordination polymer involving vanadium(IV) and 2,6-naphthalenedicarboxylato ligand.