Bis(isonicotinamide-kappa N-1)bis[4-(methylamino)benzoato]zinc(II) monohydrate

HÖKELEK, TUNCER; DAL, HAKAN; Tercan, Baris; Aybirdi, Ozgur; NECEFOĞLU, HACALİ

doi:10.1107/s1600536809041208

Bis(isonicotinamide-kappa N-1)bis[4-(methylamino)benzoato]zinc(II) monohydrate

Atıf İçin Kopyala

HÖKELEK T., DAL H., Tercan B., Aybirdi O., NECEFOĞLU H.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.65, 2009 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 65
Basım Tarihi: 2009
Doi Numarası: 10.1107/s1600536809041208
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Anadolu Üniversitesi Adresli: Evet

Özet

In the title Zn-II complex, [Zn(C8H8NO2)(2)(C6H6N2O)(2)]center dot H2O, the Zn atom is coordinated by two 4-methylaminobenzoate (MAB) and two isonicotinamide (INA) ligands in a distorted trigonal-bipyramidal geometry; one of the MAB ions acts as a bidentate ligand while the other MAB and the two INA are monodentate ligands. The dihedral angles between the carboxyl groups and the adjacent benzene rings are 8.52 (22) and 5.10 (14)degrees. In the crystal, intermolecular O-H center dot center dot center dot O and N-H center dot center dot center dot O hydrogen bonding links the molecules into a supramolecular structure. Weak intermolecular C-H center dot center dot center dot O interactions are also present.