Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene


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İBİŞOĞLU H., Ciftci G. Y., KILIÇ A., TANRIVERDİ EÇİK E., Un I., DAL H., ...Daha Fazla

JOURNAL OF CHEMICAL SCIENCES, cilt.121, sa.2, ss.125-135, 2009 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 121 Sayı: 2
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1007/s12039-009-0014-y
  • Dergi Adı: JOURNAL OF CHEMICAL SCIENCES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.125-135
  • Anahtar Kelimeler: Cyclotetraphosphazenes, P-31 NMR spectroscopy, amino phosphazenes, spiro-phosphazene, X-ray, PHOSPHORUS-NITROGEN COMPOUNDS, CRYSTAL-STRUCTURE, ANSA DILEMMA, SPIROCYCLIC CYCLOTRIPHOSPHAZENES, CYCLOPHOSPHAZENES, SPERMIDINE, ANSWER, P-31
  • Anadolu Üniversitesi Adresli: Evet

Özet

Nucleophilic substitution reactions of N4P4Cl8, with di-, tri-, and tetra-functional reagents such as N-methyl-1,3-propanediamine, N,N'-methyl-1,3-propanediamine, spermidine and spermine were investigated in this study. Six novel products were isolated whose structures have been characterized by elemental analysis, mass spectrometry, H-1 and P-31 NMR spectroscopy. The structure of (11) was investigated by X-ray crystallography.