Formation of novel spiro, spiroansa and dispiroansa derivatives of cyclotetraphosphazene from the reactions of polyfunctional amines with octachlorocyclotetraphosphazatetraene

Creative Commons License

İBİŞOĞLU H., Ciftci G. Y., KILIÇ A., TANRIVERDİ EÇİK E., Un I., DAL H., ...Daha Fazla

JOURNAL OF CHEMICAL SCIENCES, cilt.121, sa.2, ss.125-135, 2009 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 121 Sayı: 2
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1007/s12039-009-0014-y
  • Dergi Adı: JOURNAL OF CHEMICAL SCIENCES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.125-135
  • Anahtar Kelimeler: Cyclotetraphosphazenes, P-31 NMR spectroscopy, amino phosphazenes, spiro-phosphazene, X-ray, PHOSPHORUS-NITROGEN COMPOUNDS, CRYSTAL-STRUCTURE, ANSA DILEMMA, SPIROCYCLIC CYCLOTRIPHOSPHAZENES, CYCLOPHOSPHAZENES, SPERMIDINE, ANSWER, P-31
  • Anadolu Üniversitesi Adresli: Evet

Özet

Nucleophilic substitution reactions of N4P4Cl8, with di-, tri-, and tetra-functional reagents such as N-methyl-1,3-propanediamine, N,N'-methyl-1,3-propanediamine, spermidine and spermine were investigated in this study. Six novel products were isolated whose structures have been characterized by elemental analysis, mass spectrometry, H-1 and P-31 NMR spectroscopy. The structure of (11) was investigated by X-ray crystallography.