Novel electrically conductive alpha-beta SiAlON/TiCN composites


AYAS E., KARA A.

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, vol.31, no.5, pp.903-911, 2011 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 31 Issue: 5
  • Publication Date: 2011
  • Doi Number: 10.1016/j.jeurceramsoc.2010.11.026
  • Journal Name: JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.903-911
  • Keywords: alpha-beta SiAlON, TiCN, Dry mixing, Electrical conductivity, Gas pressure sintering (GPS), SILICON-NITRIDE, PERCOLATION, CERAMICS, MICROSTRUCTURE, SI3N4-MOSI2, RESISTIVITY, PARTICLES, ADDITIVES, SI3N4, HARD
  • Anadolu University Affiliated: Yes

Abstract

Electrically conductive alpha-beta SiAlON/TiCN composites were produced in the form of a segregated network in a ceramic matrix structure. A continuous 3D network of conductive TiCN particles was successfully achieved by mechanically coating spray-dried SiAlON granules with varying amounts of nano sized TiCN (0-10 vol.%) particles. For comparison, the same SiAlON matrix was incorporated with 25 vol.% micron sized TiCN particles to give a particle reinforced composite. Densification, together with mechanical and electrical properties of the composites produced were discussed in terms of conventional and novel approach. Fully dense composites were obtained by gas pressure sintering (GPS) under a nitrogen pressure of 100 bar at a peak temperature of 1990 degrees C. The electrical resistivity of the SiAlON (1 x 10(13) Omega m) matrix material was drastically reduced with the addition of only 5 vol.% TiCN (18 x 10(-4) Omega m) to the composites prepared by the coating method. (C) 2010 Elsevier Ltd. All rights reserved.