Vibrational spectroscopic study on some Hofmann type clathrates: M(1-Phenylpiperazine)(2)Ni(CN)(4)center dot 2G (M = Ni, Co and Cd; G = aniline)

PARLAK C., Alver O., ŞENYEL M.

JOURNAL OF MOLECULAR STRUCTURE, cilt.919, sa.1-3, ss.41-46, 2009 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 919 Sayı: 1-3
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1016/j.molstruc.2008.08.005
  • Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.41-46
  • Anahtar Kelimeler: Hofmann type clathrates, Inclusion compounds, 1-Phenylpiperazine, Aniline, IR and Raman spectra, HOST-GUEST INTERACTIONS, INCLUSION-COMPOUNDS, FT-IR, COMPLEXES, BENZENE, 1-PHENYLPIPERAZINE, DECOMPOSITION, PHENANTHRENE, NAPHTHALENE, ANTHRACENE
  • Anadolu Üniversitesi Adresli: Evet

Özet

New Hofmann type aniline clathrates in the form of M(PP)(2)Ni(CN)(4)center dot 2G (where pp = 1-phenylpiperazine, G = aniline and M = Ni. Co and Cd) have been prepared in powder form and FT-IR and Raman spectra have been reported. The thermal behaviour of these clathrates has been investigated by thermo-gravimetric analysis (TGA) and differential thermal analysis (DTA). The results suggest that these compounds are similar in structure to the Hofmann type clathrates and their structures consist of corrugated polymeric layers of vertical bar M-Ni(CN)(4)vertical bar(sic) with the pp spanned between two metal (M) atoms, of the consecutive two layers. (c) 2008 Elsevier B.V. All rights reserved.