Vibrational spectroscopic study on some Hofmann-T-d type clathrates: Ni(4-phenylpyridine)(2)M(CN)(4)center dot 2G (M = Cd or Hg, G=1,4-dioxane)

PARLAK C., ALVER Ö., ŞENYEL M.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, cilt.78, sa.5, ss.1487-1491, 2011 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 78 Sayı: 5
  • Basım Tarihi: 2011
  • Doi Numarası: 10.1016/j.saa.2011.01.038
  • Dergi Adı: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.1487-1491
  • Anahtar Kelimeler: Hofmann-T-d type clathrates, Vibrational spectra, 4-Phenylpyridine, 1,4-Dioxane, CRYSTAL-STRUCTURES, INFRARED-SPECTRA, RAMAN-SPECTRA, COMPLEXES, TETRACYANOCADMATE(II), 4-PHENYLPYRIDINE, TRANSITION, K2CD(CN)4, K2HG(CN)4
  • Anadolu Üniversitesi Adresli: Evet

Özet

New Hofmann-T-d type clathrates in the form of Ni(4-Phpy)(2)M(CN)(4)center dot 2G (where 4-Phpy = 4-phenylpyridine, M = Cd or Hg and G = 1,4-dioxane) have been prepared in powder form and their FT-IR and Raman spectra have been reported. The results suggest that these compounds are similar in structure to the Hofmann-T-d type clathrates. (C) 2011 Elsevier B.V. All rights reserved.