Vibrational spectroscopic study on some Hofmann-T-d type clathrates: Ni(4-phenylpyridine)(2)M(CN)(4)center dot 2G (M = Cd or Hg, G=1,4-dioxane)

PARLAK C., ALVER Ö., ŞENYEL M.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, vol.78, no.5, pp.1487-1491, 2011 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 78 Issue: 5
  • Publication Date: 2011
  • Doi Number: 10.1016/j.saa.2011.01.038
  • Journal Name: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.1487-1491
  • Keywords: Hofmann-T-d type clathrates, Vibrational spectra, 4-Phenylpyridine, 1,4-Dioxane, CRYSTAL-STRUCTURES, INFRARED-SPECTRA, RAMAN-SPECTRA, COMPLEXES, TETRACYANOCADMATE(II), 4-PHENYLPYRIDINE, TRANSITION, K2CD(CN)4, K2HG(CN)4
  • Anadolu University Affiliated: Yes

Abstract

New Hofmann-T-d type clathrates in the form of Ni(4-Phpy)(2)M(CN)(4)center dot 2G (where 4-Phpy = 4-phenylpyridine, M = Cd or Hg and G = 1,4-dioxane) have been prepared in powder form and their FT-IR and Raman spectra have been reported. The results suggest that these compounds are similar in structure to the Hofmann-T-d type clathrates. (C) 2011 Elsevier B.V. All rights reserved.