One-dimensional cyano-bridged heterometallic (Cu/Ni and Cu/Pd) complexes with 1-ethylimidazole

Cetinkaya F., KÜRKÇÜOĞLU G. S., YEŞİLEL O. Z., Hokelek T., DAL H.

POLYHEDRON, vol.47, no.1, pp.126-133, 2012 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 47 Issue: 1
  • Publication Date: 2012
  • Doi Number: 10.1016/j.poly.2012.08.041
  • Journal Name: POLYHEDRON
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.126-133
  • Keywords: Heterometallic complexes, Cyano-bridged complexes, Tetracyanonickelate(II), Tetracyanopalladate(II), 1-Ethylimidazole complexes, CRYSTAL-STRUCTURE, COPPER(II) COMPLEXES, MAGNETIC-PROPERTIES, NI, PD, 4-METHYLIMIDAZOLE, CONSTANTS, SPECTRUM, IONS
  • Anadolu University Affiliated: Yes


Two new cyano-bridged heteronuclear polymeric complexes, {[Cu(etim)(4)Ni(mu-CN)(2)(CN)(2)]center dot H2O}(n) (1) and [Cu(etim)(4)Pd(mu-CN)(2)(CN)(2)](n) (2) (etim = 1-ethylimidazole) were synthesized and characterized by FT-IR and Raman spectroscopies, thermal (TG. DIG and DTA) and elemental analyses and single crystal X-ray diffraction techniques. They crystallize in the triclinic system and P (1) over bar space group. The two compounds are isostructural, and their crystal structures are formed by quasi-linear chains exhibiting [-Cu(etim)(4)-mu-NC-M(CN)(2)-mu-CN-](n) composition. The Ni(II) or Pd(II) ions is four coordinate with four cyanide-carbon atoms in a square planar geometry and the Cu(II) ion exhibits a distorted octahedral coordination by four etim ligands and two bridging cyano groups. (C) 2012 Elsevier Ltd. All rights reserved.