FT-IR spectroscopic investigation of some Hofmann type complexes: M(2-(1-Cyclohexenyl)ethylamine)(2)Ni(CN)(4) (M = Ni, Co)

İZGİ T., PARLAK C., Aytekin T., ŞENYEL M.

JOURNAL OF MOLECULAR STRUCTURE, vol.892, no.1-3, pp.311-315, 2008 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 892 Issue: 1-3
  • Publication Date: 2008
  • Doi Number: 10.1016/j.molstruc.2008.05.041
  • Journal Name: JOURNAL OF MOLECULAR STRUCTURE
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.311-315
  • Keywords: Hofmann type complexes, 2-(1-Cyclohexenyl)ethylamine, Infrared spectra, DTA, TGA, METAL(II) TETRACYANONICKELATE COMPLEXES, MOLECULE INCLUSION-COMPOUNDS, CRYSTAL-STRUCTURES, BENZENE, CD, 1,5-DIAMINOPENTANE, PHENANTHRENE, NAPHTHALENE, ANTHRACENE, CLATHRATE
  • Anadolu University Affiliated: Yes

Abstract

New Hofmann type complexes in the form of M(CyHEA)(2)Ni(CN)(4) (where CyHEA = 2-(1-cyclohexenyl)ethylamine; M = Ni or Co) have been prepared in powder form and their infrared spectra have been reported in the range of 4000-400 cm(-1). The thermal behaviour of these complexes has been investigated by differential thermal analysis (DTA) and thermo-gravimetric analysis (TGA). The results suggest that these compounds are similar in structure to Hofmann type complexes and their structures consist of polymeric layers vertical bar M-Ni(CN)(4)vertical bar(infinity) with the CyHEA molecule bound to the metal atom (M). (C) 2008 Published by Elsevier B.V.