Crystal structure of aquabis(heptafluorobutanoato-kappa O)(1,10 '-phenanthroline-kappa N-2,N ')copper(II)

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KANİ İ.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.72, ss.4-14, 2016 (ESCI) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 72
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1107/s2056989015022720
  • Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
  • Sayfa Sayıları: ss.4-14
  • Anahtar Kelimeler: crystal structure, copper(II) complex, heptafluorobutanoic acid, o-phenanthroline, hydrogen bonding, COMPLEXES, LIGANDS, N,N)COPPER(II)
  • Anadolu Üniversitesi Adresli: Evet

Özet

The title compound, [Cu(C4F7O2)(2)(C12H8N2)(H2O)], is mononuclear and contains a pentacoordinated Cu-II ion. The geometry of Cu-II ion can be described as distorted square-pyramidal with two O atoms of two butanoate anions and two N atoms of the o-phenanthroline ligand occupying the basal plane, and a water O atom located at the axial position. In the crystal, C-H center dot center dot center dot(O,F) and O-H center dot center dot center dot(O,F) hydrogen bonds and pi-pi interactions [centroidto-centroid distance 3.533 (2) angstrom] link the molecules into a three-dimensional supramolecular structure.