Crystal structure of aquabis(heptafluorobutanoato-kappa O)(1,10 '-phenanthroline-kappa N-2,N ')copper(II)

Creative Commons License

KANİ İ.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.72, pp.4-14, 2016 (ESCI) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 72
  • Publication Date: 2016
  • Doi Number: 10.1107/s2056989015022720
  • Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
  • Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
  • Page Numbers: pp.4-14
  • Keywords: crystal structure, copper(II) complex, heptafluorobutanoic acid, o-phenanthroline, hydrogen bonding, COMPLEXES, LIGANDS, N,N)COPPER(II)
  • Anadolu University Affiliated: Yes

Abstract

The title compound, [Cu(C4F7O2)(2)(C12H8N2)(H2O)], is mononuclear and contains a pentacoordinated Cu-II ion. The geometry of Cu-II ion can be described as distorted square-pyramidal with two O atoms of two butanoate anions and two N atoms of the o-phenanthroline ligand occupying the basal plane, and a water O atom located at the axial position. In the crystal, C-H center dot center dot center dot(O,F) and O-H center dot center dot center dot(O,F) hydrogen bonds and pi-pi interactions [centroidto-centroid distance 3.533 (2) angstrom] link the molecules into a three-dimensional supramolecular structure.