Crystal structure of aquabis(heptafluorobutanoato-kappa O)(1,10 '-phenanthroline-kappa N-2,N ')copper(II)
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, vol.72, pp.4-14, 2016 (ESCI, Scopus)
- Publication Type: Article / Article
- Volume: 72
- Publication Date: 2016
- Doi Number: 10.1107/s2056989015022720
- Journal Name: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
- Journal Indexes: Emerging Sources Citation Index (ESCI), Scopus
- Page Numbers: pp.4-14
- Keywords: crystal structure, copper(II) complex, heptafluorobutanoic acid, o-phenanthroline, hydrogen bonding, COMPLEXES, LIGANDS, N,N)COPPER(II)
- Open Archive Collection: AVESIS Open Access Collection
- Anadolu University Affiliated: Yes
Abstract
The title compound, [Cu(C4F7O2)(2)(C12H8N2)(H2O)], is mononuclear and contains a pentacoordinated Cu-II ion. The geometry of Cu-II ion can be described as distorted square-pyramidal with two O atoms of two butanoate anions and two N atoms of the o-phenanthroline ligand occupying the basal plane, and a water O atom located at the axial position. In the crystal, C-H center dot center dot center dot(O,F) and O-H center dot center dot center dot(O,F) hydrogen bonds and pi-pi interactions [centroidto-centroid distance 3.533 (2) angstrom] link the molecules into a three-dimensional supramolecular structure.