Synthesis of an F-BODIPY [2]catenane using the chemistry of bis(dipyrrinato) metal complexes

NİŞANCI B., Sahinoglu S., Tuner E., Arik M., KANİ İ., DAŞTAN A., ...More

CHEMICAL COMMUNICATIONS, vol.53, no.92, pp.12418-12421, 2017 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 53 Issue: 92
  • Publication Date: 2017
  • Doi Number: 10.1039/c7cc07021g
  • Journal Name: CHEMICAL COMMUNICATIONS
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Page Numbers: pp.12418-12421
  • Anadolu University Affiliated: Yes

Abstract

ML2 type complexes of an olefin terminated 5H-dipyrrin ligand can be subjected to twofold ring closing metathesis to give bis(dipyrrinato)copper(II) and bis(dipyrrinato) zinc(II) [2] catenates. Demetalation of the copper(II) [2] catenate with KCN/N2H4 center dot H2O gave the corresponding bis(dipyrrin) [2] catenand. The boron difluoride complex of this bis(dipyrrin) was obtained as the first fluorescent F-BODIPY [2] catenane.