(mu-Perfluorosebacato-kappa O-2 : O ')bis[aquabis(1,10-phenanthroline-kappa N-2,N ')zinc(II)] perfluorosebacate bis[triaqua(perfluorosebacato-kappa O)(1,10-phenanthroline-kappa N-2,N ')zinc(II)] 3.32-hydrate

Ibrahim, Kani; Sahin, ONUR; Filiz, Yilmaz; Buyukgungor, Orhan

doi:10.1107/s1600536806027656

(mu-Perfluorosebacato-kappa O-2 : O ')bis[aquabis(1,10-phenanthroline-kappa N-2,N ')zinc(II)] perfluorosebacate bis[triaqua(perfluorosebacato-kappa O)(1,10-phenanthroline-kappa N-2,N ')zinc(II)] 3.32-hydrate

Atıf İçin Kopyala

Ibrahim K., Sahin O., Filiz Y., Buyukgungor O.

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.62, 2006 (SCI-Expanded)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 62
Basım Tarihi: 2006
Doi Numarası: 10.1107/s1600536806027656
Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
Anadolu Üniversitesi Adresli: Hayır

Özet

The asymmetric unit of the title compound, [Zn-2{O2C(CF2)(8)CO2}(C12H8N2)(4)(H2O)(2)](C10F16O4)center dot[Zn{O2C(CF2)(8)CO2}(C12H8N2)(H2O)(3)]center dot 3.32H(2)O, contains a neutral mononuclear [ZnL(phen)(H2O)3] complex (phen is 1,10-phenanthroline and L is perfluorosebacate), one half each of a centrosymmetric [Zn2L(phen)(4)(H2O)(2)](2+) binuclear complex and an uncoordinated centrosymmetric L ligand, and 1.66 water molecules of solvation. The Zn-II atoms in both the mononuclear and the binuclear complexes are six-coordinated in a distorted octahedral geometry.