Synthesis and non-linear optical properties of monopyrrolotetrathiafulvalene derived donor-pi-acceptor dyads
JOURNAL OF MATERIALS CHEMISTRY, vol.14, no.2, pp.179-184, 2004 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 14 Issue: 2
- Publication Date: 2004
- Doi Number: 10.1039/b310733g
- Journal Name: JOURNAL OF MATERIALS CHEMISTRY
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.179-184
- Anadolu University Affiliated: No
Abstract
The synthesis of novel donor-pi-acceptor dyads based on a pyrrolo-annelated tetrathiafulvalene unit is described. The linear and non-linear optical properties of these chromophores have been investigated, together with their redox properties. For a dyad containing a p-nitrophenyl acceptor group, a significant third-order optical non-linearity is observed.