FT-IR spectroscopic study of the Hofmann-T-d-type clathrates: Ni(1,9-diaminononane)M'(CN)(4).2G (M' = Cd or Hg, G = benzene, 1,2-dichlorobenzene or 1,4-dichlorobenzene)

Kartal Z., PARLAK C., Senturk S., Aytekin M. T., Senyel M.

CROATICA CHEMICA ACTA, vol.80, no.1, pp.9-15, 2007 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 80 Issue: 1
  • Publication Date: 2007
  • Journal Name: CROATICA CHEMICA ACTA
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.9-15
  • Keywords: 1,9-diaminononane, 1,2-dichlorobenzene, 1,4-dichlorobenzene, benzene, Hofmann T-d-type clathrates, infrared spectra, VIBRATIONAL-SPECTRA, DISUBSTITUTED COMPOUNDS, INCLUSION-COMPOUNDS, CRYSTAL-STRUCTURE, COMPLEXES, DERIVATIVES, M=MN, K2HG(CN)4, K2CD(CN)4, HOSTS
  • Anadolu University Affiliated: Yes

Abstract

New Hofmann T-d-type clathrates in the form of Ni(1,9-diaminononane)M'(CN)(4) center dot 2G (M' = Cd or Hg, G = benzene, 1,2-dichlorobenzene or 1,4-dichlorobenzene) were prepared in powder form and their infrared spectra are reported in the range of 4000-200 cm(-1). As seen from the spectral features, the present compounds are similar in structure to the Hofmann Td-type clathrates.