Synthesis and vibrational spectroscopic analysis of some Hofmann type clathrates

PARLAK C., ŞENYEL M.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, vol.82, no.1, pp.383-388, 2011 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 82 Issue: 1
  • Publication Date: 2011
  • Doi Number: 10.1016/j.saa.2011.07.067
  • Journal Name: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.383-388
  • Keywords: Hofmann type clathrates, Vibrational spectra, 1-Phenylpiperazine, 1,4-Dioxane, FT-IR, CD, COMPLEXES, SPECTRA, MN, NI, HG, CO
  • Anadolu University Affiliated: Yes

Abstract

New Hofmann type clathrates in the form of M(pp)(2)Ni(CN)(4)center dot 2G (where pp = 1-phenylpiperazine, G = 1,4-dioxane and M = Ni, Co or Cd) have been prepared in powder form and their FT-IR and FT-Raman spectra are reported. The results suggest that the present compounds are similar in structure to the Hofmann type clathrates and their structures consist of conjugated polymeric layers of vertical bar M-Ni(CN)(4)vertical bar(infinity) with the pp bound to the metal (M) atom. (C) 2011 Elsevier B.V. All rights reserved.