The reaction of thiophenoxide with amino-substituted chloro-cyclotriphosphazenes

İBİŞOĞLU H., DAL H., HÖKELEK T., KILIÇ A., Un I., Vardi S.

POLYHEDRON, cilt.28, sa.14, ss.2863-2870, 2009 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 28 Sayı: 14
  • Basım Tarihi: 2009
  • Doi Numarası: 10.1016/j.poly.2009.06.033
  • Dergi Adı: POLYHEDRON
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Index Chemicus (IC)
  • Sayfa Sayıları: ss.2863-2870
  • Anahtar Kelimeler: (31)P NMR, Aminocyclotriphosphazene, Hexachlorocyclotriphosphazatriene, Thiophenol, Reaction mechanism, PHOSPHORUS-NITROGEN COMPOUNDS, HEXACHLOROCYCLOTRIPHOSPHAZATRIENE, PHOSPHAZENES, CRYSTAL
  • Anadolu Üniversitesi Adresli: Evet

Özet

In the present work, a series of aminocyclotriphosphazene containing sulfur group compounds have been synthesised and characterised by elemental analysis, mass (MS), (1)H and (31)P NMR spectroscopies. The formation of thiophenoxy-substituted aminocyclotriphosphazenes could be explained by different mechanisms based on primary or secondary amino-substituted cyclotriphosphazenes. Compounds 3, 5 and 7 could be formed by a proton abstraction-chloride elimination and 9, 11 and 13 may be constituted both the S(N)(2) and S(N)(1) reaction mechanisms, respectively. These mechanisms are supported by the crystal structures of 5 and 13. Molecular and crystal structures of 5 and 13 have been characterised by X-ray crystallography. The structures of 5 and 13 are monoclinic and have space groups P2(1)/n. (C) 2009 Elsevier Ltd. All rights reserved.