FT-IR spectroscopic study of the Hofmann-Td-type clathrates: Ni(1,9-diaminononane)M′(CN)4·2G (M′ = Cd or Hg, G = benzene, 1,2-dichlorobenzene or 1,4-dichlorobenzene)

Kartal Z., PARLAK C., Şentürk Ş., Aytekin M. T., ŞENYEL M.

Croatica Chemica Acta, vol.80, no.1, pp.9-15, 2007 (SCI-Expanded) identifier

  • Publication Type: Article / Article
  • Volume: 80 Issue: 1
  • Publication Date: 2007
  • Journal Name: Croatica Chemica Acta
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.9-15
  • Keywords: 1,2-dichlorobenzene, 1,4-dichlorobenzene, 1,9-diaminononane, Benzene, Hofmann Td-type clathrates, Infrared spectra
  • Anadolu University Affiliated: Yes

Abstract

New Hofmann Td-type clathrates in the form of Ni(1,9-diaminononane)M′(CN)4·2G (M′ = Cd or Hg, G = benzene, 1,2-dichlorobenzene or 1,4-dichlorobenzene) were prepared in powder form and their infrared spectra are reported in the range of 4000-200 cm -1. As seen from the spectral features, the present compounds are similar in structure to the Hofmann Td-type clathrates.