Acid treated mordenites as adsorbents of C2H4 and H-2 gases

ERDOĞAN ALVER B., Esenli R. F.

MICROPOROUS AND MESOPOROUS MATERIALS, cilt.244, ss.67-73, 2017 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 244
  • Basım Tarihi: 2017
  • Doi Numarası: 10.1016/j.micromeso.2017.02.039
  • Dergi Adı: MICROPOROUS AND MESOPOROUS MATERIALS
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.67-73
  • Anahtar Kelimeler: Adsorption, BET, Ethylene, Hydrogen, Mordenite, XRD, XRF, H-MORDENITE, PHYSICOCHEMICAL PROPERTIES, ADSORPTION EQUILIBRIUM, CATALYTIC-PROPERTIES, HYDROGEN ADSORPTION, NATURAL ZEOLITES, CARBON-DIOXIDE, ETHYLENE, DEALUMINATION, ETHANE
  • Anadolu Üniversitesi Adresli: Hayır

Özet

In this study, a mordenite-rich tuff (M) from the Sile region (NW Turkey) was treated with HNO3 and H2SO4 at various concentrations (1.0, 3.0 and 5.0 M) at 80 degrees C for 3 h. The adsorption properties of ethylene (C2H4) and hydrogen (H-2) on natural and that of acid forms were examined experimentally at 273 and 77 K and up to 100 kPa using volumetric instrument, respectively. All the samples were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), and nitrogen (N-2) adsorption methods. Some differences on XRD pattern were signed in between natural and acid modified samples according to the intensity, sharpness and crystallite degree of mordenite peaks. C2H4 and H-2 adsorption capacities of the original and acid treated mordenites were in the range of 0.762-0.876 mmol cland 1.373 1.672 mmol g(-1) at 273 and 77 K, respectively. The increasing retention values of C2H4 and H-2 after the acid treatments were analyzed in comparison with the structural changes. (C) 2017 Elsevier Inc. All rights reserved.