FT-IR spectroscopic study on some 4-(3-cyclohexen-1-yl)pyridine Metal(II) tetracyanonickelate complexes

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Senturk S., PARLAK C., Aytekin M., Senyel M.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, vol.60, no.7, pp.532-536, 2005 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 60 Issue: 7
  • Publication Date: 2005
  • Doi Number: 10.1515/zna-2005-0711
  • Journal Name: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.532-536
  • Keywords: Hofmann-type complexes, tetracyanonickelate, 4-(3-cyclohexen-1-yl)pyridine, infrared spectra, HOFMANN-TYPE BENZENE, SPECTRA, CYCLOHEXENE, STABILITY, LATTICE
  • Anadolu University Affiliated: No

Abstract

New Hofmann-type complexes in the form of M(4-Chpy)(2)Ni(CN)(4) [where 4-Chpy = 4-(3-cyclohexen-1-yl)pyridine and M = Ni, Co] were prepared in powder form, and their infrared spectra are reported in the range of 4000-400 cm(-1). The spectral findings suggest that these compounds are similar in structure to the Hofmann-type complexes, and their structure consists of polymeric layers vertical bar M-Ni(CN)(4)vertical bar(infinity) with the 4-(3-cyclohexen-1-yl)pyridine molecule bound to the metal atom(M).