FT-IR spectroscopic study on some 4-(3-cyclohexen-1-yl)pyridine Metal(II) tetracyanonickelate complexes

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Senturk S., PARLAK C., Aytekin M., Senyel M.

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, cilt.60, sa.7, ss.532-536, 2005 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 60 Sayı: 7
  • Basım Tarihi: 2005
  • Doi Numarası: 10.1515/zna-2005-0711
  • Dergi Adı: ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.532-536
  • Anahtar Kelimeler: Hofmann-type complexes, tetracyanonickelate, 4-(3-cyclohexen-1-yl)pyridine, infrared spectra, HOFMANN-TYPE BENZENE, SPECTRA, CYCLOHEXENE, STABILITY, LATTICE
  • Anadolu Üniversitesi Adresli: Hayır

Özet

New Hofmann-type complexes in the form of M(4-Chpy)(2)Ni(CN)(4) [where 4-Chpy = 4-(3-cyclohexen-1-yl)pyridine and M = Ni, Co] were prepared in powder form, and their infrared spectra are reported in the range of 4000-400 cm(-1). The spectral findings suggest that these compounds are similar in structure to the Hofmann-type complexes, and their structure consists of polymeric layers vertical bar M-Ni(CN)(4)vertical bar(infinity) with the 4-(3-cyclohexen-1-yl)pyridine molecule bound to the metal atom(M).