Synthesis and characterization of a novel 3-amino-1,2,4-triazole lead(II) coordination polymer

Creative Commons License

SÖZERLİ Ş. E., Ozen A., KANİ İ., DEMİR D.

TURKISH JOURNAL OF CHEMISTRY, vol.38, no.4, pp.671-678, 2014 (SCI-Expanded) identifier identifier

  • Publication Type: Article / Article
  • Volume: 38 Issue: 4
  • Publication Date: 2014
  • Doi Number: 10.3906/kim-1308-19
  • Journal Name: TURKISH JOURNAL OF CHEMISTRY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus, TR DİZİN (ULAKBİM)
  • Page Numbers: pp.671-678
  • Keywords: 3-Amino-1,2,4-triazole, 1,2,4-triazole, acetate, lead(II) complexes, coordination polymer, ORGANIC FRAMEWORK MATERIALS, CRYSTAL-STRUCTURE, PB(II) COORDINATION, EMISSION PROPERTIES, LIGANDS, COMPLEX, 2,2'-BIPYRIDINE, CARBOXYLATE, DICARBOXYLATE, CONSTRUCTION
  • Anadolu University Affiliated: Yes

Abstract

A novel [Pb-2(mu-atrz)(2)(mu-CH3COO)(CH3COO)](n) (atrz = 3 amino-1,2,4-triazole) complex was synthesized and characterized by IR spectroscopy, thermogravimetric analysis, and single crystal X-ray diffraction. The molecular structure shows that the complex is a coordination polymer in which there are 2 different lead(II) ions with coordination number of 5, Pb(2), and, with a coordination number of 4, Pb(1). Each atrz acts as a bridging ligand between 2 Pb(II) ions through the 2 adjacent nitrogen atoms of the triazole ring. The acetate anions show different types of coordination mode: one acts as a bridge by coordination of the same oxygen atom with Pb(II) ions and the other as a monodentate coordination by one of the oxygen atoms with Pb(2).