An infrared spectroscopic study on the Hofmann-diam-type 1,12-diaminododecanemetal(II) tetracyanonickelate(II)-aromatic guest clathrates: M(H2N(CH2)(12)NH2)Ni(CN)(4)center dot G(M=Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl)
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, vol.39, no.1-2, pp.175-180, 2001 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 39 Issue: 1-2
- Publication Date: 2001
- Doi Number: 10.1023/a:1008141726024
- Journal Name: JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.175-180
- Keywords: Hofmann-type clathrates, tetracyanonickelate, 1,12-diaminododecane, infrared spectra, benezene, naphthalene, anthracene, phenanthrene biphenyl, SPECTRA, CO
- Anadolu University Affiliated: No
Abstract
Three Hofmann-diaminododecane-type clathrates of the form M(1,12-diaminododecane) Ni(CN)(4).G (M = Co, Ni or Cd; G = benzene, naphthalene, anthracene, phenanthrene or biphenyl) have been prepared in powder form. The 1,12-diaminododecane molecules in the host lattice permit the inclusion of bulky guest molecules. The spectral features suggest that these compounds are similar in structure to the other Hofmann-diam-type clathrates.