Crystal structure of bis(mu-2-benzoylbenzoato-kappa O-2:O')bis[bis(2,2'-bipyridine-kappa N-2,N')manganese(II)] bis(perchlorate)
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, cilt.71, 2015 (ESCI, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 71
- Basım Tarihi: 2015
- Doi Numarası: 10.1107/s2056989015023671
- Dergi Adı: ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS
- Derginin Tarandığı İndeksler: Emerging Sources Citation Index (ESCI), Scopus
- Anahtar Kelimeler: crystal structure, manganese(II) complex, benzoylbenzoate, 2,2'-bipyridine, hydrogen bonding., METAL-ORGANIC FRAMEWORKS, COORDINATION POLYMERS, GAS SORPTION, 2,2'-BIPYRIDINE
- Anadolu Üniversitesi Adresli: Evet
Özet
The title compound, [Mn-2(C6H5COC6H4COO)(2)(C10H8N2)(4)](ClO4)(2), comprises a centrosymmetric binuclear cation and two perchlorate anions. In the complex cation, two Mn-II atoms are bridged by two 0 atoms of two different 2-benzoyl-benzoate ligands, each Mn-II atom being further coordinated by two 2,2'-bipyridine (bipy) ligands in a distorted octahedral environment. Within the binuclear molecule, the Mn center dot center dot center dot Mn separation is 4.513 (7) angstrom. Intermolecular C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions link the molecules into a three-dimensional network.