Vibrational spectroscopic investigations of some Hofmann-T-d-type complexes: Ni(2-(1-cyclohexenyl)ethylamine)(2)M(CN)(4) (M = Cd or Hg)

İZGİ T., PARLAK C., ŞENYEL M.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, vol.76, no.5, pp.435-438, 2010 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 76 Issue: 5
  • Publication Date: 2010
  • Doi Number: 10.1016/j.saa.2009.10.043
  • Journal Name: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.435-438
  • Keywords: 2-(1-Cyclohexenyl)ethylamine, IR and Raman spectra, Hofmann-T-d-type complexes, FT-IR, CRYSTAL-STRUCTURES, K2CD(CN)4, K2HG(CN)4, BENZENE, NI, CO
  • Anadolu University Affiliated: Yes

Abstract

New Hofmann-T-d- type complexes in the form of Ni(CyHEA)(2)M(CN)(4) (where CyHEA = 2-(1-cyclohexenyl)ethylamine and M = Cd or Hg) have been prepared in powder form and their infrared (4000-100 cm(-1)) and Raman (2800-1650 cm(-1)) spectra have been reported. The thermal behaviour of these complexes has been investigated by differential thermal analysis (DTA) and thermo-gravimetric analysis (TGA). The results suggest that these compounds are similar in structure to the Hofmann-T-d-type complexes. (C) 2009 Elsevier B.V. All rights reserved.