Vibrational spectroscopic investigations of some Hofmann-T-d-type complexes: Ni(2-(1-cyclohexenyl)ethylamine)(2)M(CN)(4) (M = Cd or Hg)
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, vol.76, no.5, pp.435-438, 2010 (SCI-Expanded, Scopus)
- Publication Type: Article / Article
- Volume: 76 Issue: 5
- Publication Date: 2010
- Doi Number: 10.1016/j.saa.2009.10.043
- Journal Name: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
- Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Page Numbers: pp.435-438
- Keywords: 2-(1-Cyclohexenyl)ethylamine, IR and Raman spectra, Hofmann-T-d-type complexes, FT-IR, CRYSTAL-STRUCTURES, K2CD(CN)4, K2HG(CN)4, BENZENE, NI, CO
- Anadolu University Affiliated: Yes
Abstract
New Hofmann-T-d- type complexes in the form of Ni(CyHEA)(2)M(CN)(4) (where CyHEA = 2-(1-cyclohexenyl)ethylamine and M = Cd or Hg) have been prepared in powder form and their infrared (4000-100 cm(-1)) and Raman (2800-1650 cm(-1)) spectra have been reported. The thermal behaviour of these complexes has been investigated by differential thermal analysis (DTA) and thermo-gravimetric analysis (TGA). The results suggest that these compounds are similar in structure to the Hofmann-T-d-type complexes. (C) 2009 Elsevier B.V. All rights reserved.