Mimicking receptor for methylmercury preconcentration based on ion-imprinting

Buyuktiryaki S., Say R., Denizli A., Ersoz A.

TALANTA, cilt.71, sa.2, ss.699-705, 2007 (SCI-Expanded) identifier identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 71 Sayı: 2
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1016/j.talanta.2006.05.026
  • Dergi Adı: TALANTA
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.699-705
  • Anahtar Kelimeler: methylmercury separation, MIP, ion-imprinting, preconcentration, mimicking receptor, SOLID-PHASE EXTRACTION, PERFORMANCE LIQUID-CHROMATOGRAPHY, ATOMIC-ABSORPTION-SPECTROMETRY, SELECTIVE SEPARATION, INORGANIC MERCURY, SODIUM TETRAETHYLBORATE, POLYMERIC MICROBEADS, AQUEOUS-SOLUTION, METHYL-MERCURY, RECOGNITION
  • Anadolu Üniversitesi Adresli: Evet

Özet

Solid-phase extraction (SPE) based on molecularly imprinted polymers (MIPs) were used to develop selective separation and preconcentration for methylmercury ion from complex matrixes. In this study, an ion-imprinting polymer was prepared to make artificial organomercury lyase preorganizing three methacryloyl-(L)-Cysteine methylester (MAC) monomers and one methylmercury ion in a three-coordinate form by template polymerization, with the goal preparing a solid-phase which has the high selectivity for methylmercury ions.