Vibrational spectroscopic study on some Hofmann type clathrates: M(2-(1-cyclohexenyl)ethylamine)(2)Ni(CN)(4)center dot 2benzene (M = Ni and Cd)

İZGİ T., PARLAK C., ŞENYEL M.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, vol.79, no.2, pp.308-311, 2011 (SCI-Expanded) identifier identifier identifier

  • Publication Type: Article / Article
  • Volume: 79 Issue: 2
  • Publication Date: 2011
  • Doi Number: 10.1016/j.saa.2010.12.044
  • Journal Name: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.308-311
  • Keywords: Hofmann type clathrates, Inclusion compounds, 2-(1-Cyclohexenyl)ethylamine, Benzene, IR and Raman spectra, FT-IR, BENZENE, CO, PHENANTHRENE, NAPHTHALENE, ANTHRACENE, COMPLEXES, ANILINE, HG
  • Anadolu University Affiliated: Yes

Abstract

New Hofmann type benzene clathrates in the form of M(CyHEA)(2)Ni(CN)(4)center dot 2benzene (where CyHEA= 2-(1-cyclohexenyl)ethylamine and M=Ni or Cd) have been prepared in powder form and FT-IR and Raman spectra have been reported. The results suggest that title compounds are similar in structure to Hofmann type clathrates and their structures consist of polymeric layers of vertical bar M-Ni(CN)(4)vertical bar(infinity) with the CyHEA molecule bounded to the metal atoms (M). (C) 2011 Published by Elsevier B.V.