Synthesis and theoretical study of bis(fluoroisatinato)mercury(II)
JOURNAL OF MOLECULAR STRUCTURE, cilt.921, sa.1-3, ss.172-177, 2009 (SCI-Expanded, Scopus)
- Yayın Türü: Makale / Tam Makale
- Cilt numarası: 921 Sayı: 1-3
- Basım Tarihi: 2009
- Doi Numarası: 10.1016/j.molstruc.2008.12.045
- Dergi Adı: JOURNAL OF MOLECULAR STRUCTURE
- Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
- Sayfa Sayıları: ss.172-177
- Anahtar Kelimeler: 5-Fluoroisatin, Bis(fluoroisatinato)mercury(II), Quantum-chemical calculation, FT-IR, UV
- Anadolu Üniversitesi Adresli: Evet
Özet
Bis(fluoroisatinato)mercury(II) was synthesised from the reaction between 5-fluoroisatin (HFI) and mercury(II) acetate in methanol. Mercury(II) coordination with nitrogen atom of 5-fluoroisatin molecule was observed using the FT-IR and NMR spectra of the product. Quantum chemistry calculations for 5-fluoroisatin (HFI) and bis(fluoroisatinato)mercury(II) (Hg(FI)(2)) were carried out. Vibrational analysis calculation at the RHF/LanL2DZ and B3LYP/LanL2DZ level was compared to the experimental solid-state data. UV-visible analyses were also Studied. (C) 2008 Elsevier B.V. All rights reserved.